{"id":32052,"date":"2014-03-15T17:08:41","date_gmt":"2014-03-15T15:08:41","guid":{"rendered":"https:\/\/oneearth-oneocean.com\/2014\/03\/15\/production-characterization-and-fuel-properties-of-alternative-diesel-fuel-from-pyrolysis-of-waste-plastic-grocery-bags\/"},"modified":"2014-03-15T17:08:41","modified_gmt":"2014-03-15T15:08:41","slug":"production-characterization-and-fuel-properties-of-alternative-diesel-fuel-from-pyrolysis-of-waste-plastic-grocery-bags","status":"publish","type":"post","link":"https:\/\/oneearth-oneocean.com\/en\/research-en\/2014\/production-characterization-and-fuel-properties-of-alternative-diesel-fuel-from-pyrolysis-of-waste-plastic-grocery-bags\/","title":{"rendered":"Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags"},"content":{"rendered":"
Brajendra K. Sharma, Bryan R. Moser, Karl E. Vermillion, Kenneth M.\nDoll, Nandakishore Rajagopalan, Production, characterization and fuel\nproperties of alternative diesel fuel from pyrolysis of waste plastic\ngrocery bags, Fuel Processing Technology, Volume 122, June 2014, Pages\n79-90, ISSN 0378-3820, http:\/\/dx.doi.org\/10.1016\/j.fuproc.2014.01.019<\/a>.\n(http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0378382014000290<\/a>)\nAbstract: Pyrolysis of HDPE waste grocery bags followed by distillation\nresulted in a liquid hydrocarbon mixture with average structure\nconsisting of saturated aliphatic paraffinic hydrogens (96.8%),\naliphatic olefinic hydrogens (2.6%) and aromatic hydrogens (0.6%) that\ncorresponded to the boiling range of conventional petroleum diesel fuel\n(#1 diesel 190&ndash;290 &deg;C and #2 diesel 290&ndash;340 &deg;C).\nCharacterization of the\nliquid hydrocarbon mixture was accomplished with gas chromatography&ndash;mass\nspectroscopy, infrared and nuclear magnetic resonance spectroscopies,\nsize exclusion chromatography, and simulated distillation. No oxygenated\nspecies such as carboxylic acids, aldehydes, ethers, ketones, or\nalcohols were detected. Comparison of the fuel properties to the\npetrodiesel fuel standards ASTM D975 and EN 590 revealed that the\nsynthetic product was within all specifications after addition of\nantioxidants with the exception of density (802 kg\/m3). Notably, the\nderived cetane number (73.4) and lubricity (198 &mu;m, 60 &deg;C, ASTM D6890)\nrepresented significant enhancements over those of conventional\npetroleum diesel fuel. Other fuel properties included a kinematic\nviscosity (40 &deg;C) of 2.96 mm2\/s, cloud point of 4.7 &deg;C, flash point of\n81.5 &deg;C, and energy content of 46.16 MJ\/kg. In summary, liquid\nhydrocarbons with appropriate boiling range produced from pyrolysis of\nwaste plastic appear suitable as blend components for conventional\npetroleum diesel fuel.\nKeywords: Plastic; Pyrolysis; High-density polyethylene; Fuel; Diesel;\nBiodiesel<\/pre>\n","protected":false},"excerpt":{"rendered":"
Brajendra K. Sharma, Bryan R. Moser, Karl E. Vermillion, Kenneth M. Doll, Nandakishore Rajagopalan, Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags, Fuel Processing Technology, Volume 122, June 2014, Pages 79-90, ISSN 0378-3820, http:\/\/dx.doi.org\/10.1016\/j.fuproc.2014.01.019. (http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0378382014000290) Abstract: Pyrolysis of HDPE waste grocery bags followed by distillation resulted in a liquid hydrocarbon mixture with average structure consisting of saturated aliphatic paraffinic hydrogens (96.8%), aliphatic olefinic hydrogens (2.6%) and aromatic hydrogens (0.6%) that corresponded to the boiling range of conventional petroleum diesel fuel (#1 diesel 190&ndash;290 &deg;C and #2 diesel 290&ndash;340 &deg;C). Characterization of the liquid hydrocarbon mixture was accomplished with gas chromatography&ndash;mass spectroscopy, infrared and nuclear magnetic resonance spectroscopies, size exclusion chromatography, and simulated distillation. No oxygenated species such as carboxylic acids, aldehydes, ethers, ketones, or alcohols were detected. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D975 and EN 590 revealed that the synthetic product was within all specifications after addition of antioxidants with the exception of density (802 kg\/m3). Notably, the derived cetane number (73.4) and lubricity (198 &mu;m, 60 &deg;C, ASTM D6890) represented significant enhancements over those of conventional petroleum diesel fuel. Other fuel properties included a kinematic viscosity (40 &deg;C) of 2.96 mm2\/s, cloud point of 4.7 &deg;C, flash point of 81.5 &deg;C, and energy content of 46.16 MJ\/kg. In summary, liquid hydrocarbons with appropriate boiling range produced from pyrolysis of waste plastic appear suitable as blend components for conventional petroleum diesel fuel. Keywords: Plastic; Pyrolysis; High-density polyethylene; Fuel; Diesel; Biodiesel<\/p>\n","protected":false},"author":7,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3504,3445,3423],"tags":[3728,3729,3730,3731,2438,3732],"yoast_head":"\nProduction, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags - One Earth - One Ocean e. V.<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/oneearth-oneocean.com\/en\/research-en\/2014\/production-characterization-and-fuel-properties-of-alternative-diesel-fuel-from-pyrolysis-of-waste-plastic-grocery-bags\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags - One Earth - One Ocean e. V.\" \/>\n<meta property=\"og:description\" content=\"Brajendra K. Sharma, Bryan R. Moser, Karl E. Vermillion, Kenneth M. Doll, Nandakishore Rajagopalan, Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags, Fuel Processing Technology, Volume 122, June 2014, Pages 79-90, ISSN 0378-3820, http:\/\/dx.doi.org\/10.1016\/j.fuproc.2014.01.019. (http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0378382014000290) Abstract: Pyrolysis of HDPE waste grocery bags followed by distillation resulted in a liquid hydrocarbon mixture with average structure consisting of saturated aliphatic paraffinic hydrogens (96.8%), aliphatic olefinic hydrogens (2.6%) and aromatic hydrogens (0.6%) that corresponded to the boiling range of conventional petroleum diesel fuel (#1 diesel 190&ndash;290 &deg;C and #2 diesel 290&ndash;340 &deg;C). Characterization of the liquid hydrocarbon mixture was accomplished with gas chromatography&ndash;mass spectroscopy, infrared and nuclear magnetic resonance spectroscopies, size exclusion chromatography, and simulated distillation. No oxygenated species such as carboxylic acids, aldehydes, ethers, ketones, or alcohols were detected. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D975 and EN 590 revealed that the synthetic product was within all specifications after addition of antioxidants with the exception of density (802 kg\/m3). Notably, the derived cetane number (73.4) and lubricity (198 &mu;m, 60 &deg;C, ASTM D6890) represented significant enhancements over those of conventional petroleum diesel fuel. Other fuel properties included a kinematic viscosity (40 &deg;C) of 2.96 mm2\/s, cloud point of 4.7 &deg;C, flash point of 81.5 &deg;C, and energy content of 46.16 MJ\/kg. In summary, liquid hydrocarbons with appropriate boiling range produced from pyrolysis of waste plastic appear suitable as blend components for conventional petroleum diesel fuel. Keywords: Plastic; Pyrolysis; High-density polyethylene; Fuel; Diesel; Biodiesel\" \/>\n<meta property=\"og:url\" content=\"https:\/\/oneearth-oneocean.com\/en\/research-en\/2014\/production-characterization-and-fuel-properties-of-alternative-diesel-fuel-from-pyrolysis-of-waste-plastic-grocery-bags\/\" \/>\n<meta property=\"og:site_name\" content=\"One Earth - One Ocean e. 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(http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0378382014000290) Abstract: Pyrolysis of HDPE waste grocery bags followed by distillation resulted in a liquid hydrocarbon mixture with average structure consisting of saturated aliphatic paraffinic hydrogens (96.8%), aliphatic olefinic hydrogens (2.6%) and aromatic hydrogens (0.6%) that corresponded to the boiling range of conventional petroleum diesel fuel (#1 diesel 190&ndash;290 &deg;C and #2 diesel 290&ndash;340 &deg;C). Characterization of the liquid hydrocarbon mixture was accomplished with gas chromatography&ndash;mass spectroscopy, infrared and nuclear magnetic resonance spectroscopies, size exclusion chromatography, and simulated distillation. No oxygenated species such as carboxylic acids, aldehydes, ethers, ketones, or alcohols were detected. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D975 and EN 590 revealed that the synthetic product was within all specifications after addition of antioxidants with the exception of density (802 kg\/m3). Notably, the derived cetane number (73.4) and lubricity (198 &mu;m, 60 &deg;C, ASTM D6890) represented significant enhancements over those of conventional petroleum diesel fuel. Other fuel properties included a kinematic viscosity (40 &deg;C) of 2.96 mm2\/s, cloud point of 4.7 &deg;C, flash point of 81.5 &deg;C, and energy content of 46.16 MJ\/kg. In summary, liquid hydrocarbons with appropriate boiling range produced from pyrolysis of waste plastic appear suitable as blend components for conventional petroleum diesel fuel. Keywords: Plastic; Pyrolysis; High-density polyethylene; Fuel; Diesel; Biodiesel","og_url":"https:\/\/oneearth-oneocean.com\/en\/research-en\/2014\/production-characterization-and-fuel-properties-of-alternative-diesel-fuel-from-pyrolysis-of-waste-plastic-grocery-bags\/","og_site_name":"One Earth - One Ocean e. 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